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Competitive adsorption and desorption of copper and lead in some soil of North China

Fengjie ZHANG, Xiaoxia OU, Shuo CHEN, Chunqiu RAN, Xie QUAN

《环境科学与工程前沿(英文)》 2012年 第6卷 第4期   页码 484-492 doi: 10.1007/s11783-012-0423-x

摘要: The competitive adsorption and desorption of Pb(II) and Cu(II) ions in the soil of three sites in North China were investigated using single and binary metal solutions with 0.01 mol·L CaCl as background electrolyte. The desorption isotherms of Pb(II) and Cu(II) were similar to the adsorption isotherms, which can be fitted well by Freundlich equation ( >0.96). The soil in the three sites had greater sorption capacities for Pb(II) than Cu(II), which was affected strongly by the soil characteristics. In the binary metal solution containing 1∶1 molar ratio of Pb(II) and Cu(II), the total amount of Pb(II) and Cu(II) adsorption was affected by the simultaneous presence of the two metal ions, indicating the existence of adsorption competition between the two metal ions. Fourier transform infrared (FT-IR) spectroscopy was used to investigate the interaction between soil and metal ions, and the results revealed that the carboxyl and hydroxyl groups in the soil were the main binding sites of metal ions.

关键词: competitive adsorption     desorption     copper     lead     soil    

Immobilized

Pei MA, Dan ZHANG

《环境科学与工程前沿(英文)》 2012年 第6卷 第4期   页码 498-508 doi: 10.1007/s11783-012-0429-4

摘要: To investigate the potential use of ( ) residue for Cd adsorption, poly alcohol Na alginate (PVA) was applied to immobilize it. The parameters including contact time, pH, adsorbent dosages, and coexisting metal ions were studied. The suitable pH for immobilized was 4–7 wider than that for raw (pH 6–7). In the presence of Pb concentration varying from 0 to 30 mg·L , the Cd adsorption ratios declined by 6.71% and 47.45% for immobilized and raw , respectively. While, with the coexisting ion Cu concentration varied from 0 to 30 mg·L , the Cd adsorption ratios declined by 12.97% and 50.56% for immobilized and raw , respectively. The Cd adsorption isotherms in single–metal and dual-metal solutions were analyzed by using Langmuir, Freundlich, and Dubinin–Radushkevich models. The Cd adsorption capacities ( ) in single-metal solution were 6.448 mg·L and 2.832 mg·L for immobilized and raw , respectively. The of immobilized were 1.850 mg Cd·g in Cd + Pb solution and 3.961 mg Cd·g in Cd + Cu solution, respectively. The Cd adsorption processes subjected to both adsorbents follow pseudo-second-order model. Mechanism study showed the functional group of was –OH, –NH, –CO, and PVA played an important role in metal adsorbing. Mining wastewater treatment test showed that PVA–SA-immobilized was effective in mixed pollutant treatment even for wastewater containing metal ions in very low concentration.

关键词: immobilization     Lentinus edodes residue     competitive adsorption     isotherm    

Adsorption of sulfonamides on lake sediments

Zhenxing ZHONG, Jian XU, Yuan ZHANG, Lei LI, Changsheng GUO, Yan HE, Wenhong FAN, Beiping ZHANG

《环境科学与工程前沿(英文)》 2013年 第7卷 第4期   页码 518-525 doi: 10.1007/s11783-013-0500-9

摘要: Sulfonamides (SAs) are one class of the most widely used antibiotics around the world. Their fate and transport in the aquatic environment is of great concern. In this study, adsorption of four SAs—sulfadiazine (SD), sulfamethoxazole (SMZ), sulfadimethoxine (SDM) and sulfamethazine (SM2)—in single-solute and multi-solute systems on sediments of Dianchi (DC) Lake and Taihu (TH) Lake, China was investigated with batch experiments. In the single-solute adsorption system, the Langmuir model and the dual-mode model described the adsorption process better than the Freundlich model. Model fitness was better on DC sediment than on TH sediment. The order of adsorption capacity approximately followed a decreasing order of SDM>SD>SM2>SMZ on both sediments, which was likely attributed to the distinctly different water solubility of the four SAs. In the multi-solute system, the order of adsorption capacity was SM2>SDM>SD>SMZ, which was probably related to the compound speciation caused by the pH values of the experimental solution. In the multi-solute system, both competitive and cooperative adsorption played important roles in the adsorption of sulfonamides on sediments.

关键词: sulfonamides     sediments     competitive adsorption     cooperative adsorption    

Effect of co-existing organic compounds on adsorption of perfluorinated compounds onto carbon nanotubes

Shubo DENG,Yue BEI,Xinyu LU,Ziwen DU,Bin WANG,Yujue WANG,Jun HUANG,Gang YU

《环境科学与工程前沿(英文)》 2015年 第9卷 第5期   页码 784-792 doi: 10.1007/s11783-015-0790-1

摘要: Co-existing organic compounds may affect the adsorption of perfluorinated compounds (PFCs) and carbon nanotubes in aquatic environments. Adsorption of perfluorooctane sulfonate (PFOS), perfluorooctane acid (PFOA), perfluorobutane sulfonate (PFBS), and perfluorohexane sulfonate (PFH S) on the pristine multi-walled carbon nanotubes (MWCNTs-Pri), carboxyl functionalized MWCNTs (MWCTNs-COOH), and hydroxyl functionalized MWCNTs (MWCNTs-OH) in the presence of humic acid, 1-naphthol, phenol, and benzoic acid was studied. Adsorption kinetics of PFOS was described well by the pseudo-second-order model and the sorption equilibrium was almost reached within 24 h. The effect of co-existing organic compounds on PFOS adsorption followed the decreasing order of humic acid>1-naphthol>benzoic acid>phenol. Adsorbed amounts of PFOS decreased significantly in the presence of co-existing or preloaded humic acid, and both adsorption energy and effective adsorption sites on the three MWCNTs decreased, resulting in the decrease of PFOS adsorption. With increasing pH, PFOS removal by three MWCNTs decreased in the presence of humic acid and phenol. The adsorbed amounts of different PFCs on the MWCNTs increased in the order of PFBS

关键词: perfluorinated compounds     carbon nanotubes     competitive adsorption     humic acid     perfluorooctane sulfonate (PFOS)    

CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

《能源前沿(英文)》 2023年 第17卷 第3期   页码 428-445 doi: 10.1007/s11708-023-0865-9

摘要: In this work, using fractured shale cores, isothermal adsorption experiments and core flooding tests were conducted to investigate the performance of injecting different gases to enhance shale gas recovery and CO2 geological storage efficiency under real reservoir conditions. The adsorption process of shale to different gases was in agreement with the extended-Langmuir model, and the adsorption capacity of CO2 was the largest, followed by CH4, and that of N2 was the smallest of the three pure gases. In addition, when the CO2 concentration in the mixed gas exceeded 50%, the adsorption capacity of the mixed gas was greater than that of CH4, and had a strong competitive adsorption effect. For the core flooding tests, pure gas injection showed that the breakthrough time of CO2 was longer than that of N2, and the CH4 recovery factor at the breakthrough time (RCH4) was also higher than that of N2. The RCH4 of CO2 gas injection was approximately 44.09%, while the RCH4 of N2 was only 31.63%. For CO2/N2 mixed gas injection, with the increase of CO2 concentration, the RCH4 increased, and the RCH4 for mixed gas CO2/N2 = 8:2 was close to that of pure CO2, about 40.24%. Moreover, the breakthrough time of N2 in mixed gas was not much different from that when pure N2 was injected, while the breakthrough time of CO2 was prolonged, which indicated that with the increase of N2 concentration in the mixed gas, the breakthrough time of CO2 could be extended. Furthermore, an abnormal surge of N2 concentration in the produced gas was observed after N2 breakthrough. In regards to CO2 storage efficiency (Sstorage-CO2), as the CO2 concentration increased, Sstorage-CO2 also increased. The Sstorage-CO2 of the pure CO2 gas injection was about 35.96%, while for mixed gas CO2/N2 = 8:2, Sstorage-CO2 was about 32.28%.

关键词: shale gas     gas injection     competitive adsorption     enhanced shale gas recovery     CO2 geological storage    

Knowledge-based competitive strategy using direct customer experience for automobile product development

Peter HODGES, Shuh Yuan LIOU,

《机械工程前沿(英文)》 2010年 第5卷 第1期   页码 33-46 doi: 10.1007/s11465-009-0080-3

摘要: The automobile product development (PD) design space continually increases in size and complexity. In this dynamic environment, firms must identify competitive strategies that maintain or increase financial return. Firms can compete on several factors including price/cost, time-to-market, or differentiation (e.g., function or quality). Here, we envision that differentiation through expertise in integration can be a successful strategy in the automotive industry. Expertise in integration requires attention to knowledge management, which is crucial for competitive advantage []. A key component of the PD process is the acquisition of data about customers’ responses to vehicle performance and the rapid use of that information in the development of new products. The paper proposes a system for collecting near real-time data about responses to vehicle performance and its integration with recent developments in design and analysis. The proposed system would collect customer psychophysical response data, correlate it with vehicle parameter response data, and apply this information with feasible design automation to provide reduced cycle time, improved quality, and greater customer satisfaction. The paper discusses some relevant technological and legal constraints and concludes that such a system is feasible, can provide a near-term competitive advantage, and in the long-term, in some form, will be necessary for success.

关键词: product development     strategy     knowledge management    

基于产业价值链的我国制造业竞争战略研究

赵文成,赵红

《中国工程科学》 2008年 第10卷 第9期   页码 54-59

摘要:

在跨国公司主导的产业价值链体系中,以寻求比较优势为目标的传统竞争战略对我国制造业竞争力产生了严重的削弱作用。研究表明,为获得可持续竞争力,我国制造业竞争战略的重点应聚焦如何建立在产业价值链中的主导和控制地位。

关键词: 产业价值链     制造业竞争战略    

Optimal production strategy for auto manufacturers with government subsidies in competitive environments

《工程管理前沿(英文)》 doi: 10.1007/s42524-023-0261-5

摘要: Using the Hotelling model and evolutionary game theory, this paper studies the optimal production strategy of duopoly auto manufacturers and explores the impacts of two government policies (manufacturer and consumer subsidies) on strategies related to the production of electric vehicles (EVs) or fuel vehicles (FVs). The study finds that consumers’ environmental preferences have direct effects on manufacturers’ market shares and profits, which in turn, affect the manufacturers’ production strategy selection. Specifically, when consumer environmental preference is sufficiently high, both auto manufacturers will eventually choose to produce EVs; when it is moderate, only one with a cost advantage will choose to produce EVs. Finally, when it is low, neither auto manufacturer will produce EVs. The findings further reveal that the more significant the difference in EV production costs is, the more inclined auto manufacturers are to choose a different final stable strategy. Regardless of whether the government subsidizes manufacturers or consumers, the policy only works if subsidies reach a certain threshold. The study also identifies the conditions under which government subsidies are considered more cost-effective.

关键词: supply chain management     low-carbon emission     electric vehicle     subsidy     evolutionary game theory    

Microcystin-LR detection based on indirect competitive enzyme-linked immunosorbent assay

SHENG Jianwu, HE Miao, YU Shaoqing, SHI Hanchang, QIAN Yi

《环境科学与工程前沿(英文)》 2007年 第1卷 第3期   页码 329-333 doi: 10.1007/s11783-007-0056-7

摘要: Microcystins (MCs) are a group of closely related toxic cyclic heptapeptides produced by common cyanobacteria, which cause lots of accidents and threatens human health. In this paper, an indirect competitive enzyme-linked immunosorbent assay (ic-ELISA) was established and used to detect microcystin-LR (MC-LR) in drinking and surface waters. The concentration of coating antigen was 5 ?g/mL, the dilution of monoclonal antibody MC10E7 was 1:3 000, the dilution of enzyme tracer (goat anti-mouse IgG-peroxidase) was 1:3 000, the standard concentration of MC-LR ranged from 0.001 μg/L to 30 μg/L, and o-phenylenediamine was used as substrate. The assay showed high relativity with high performance liquid chromatography (HPLC) with a correlation coefficient of more than 99%. The relative standard deviation was less than 10%, the detection limit was achieved down to 0.01 μg/L and up to 5.1 μg/L. The quantitative detection range was from 0.03 μg/L to 3 μg/L, and the antibody had high specificity for [4-arginine] microcystins. It performed well in spite of the influence of the real samples.

关键词: o-phenylenediamine     4-arginine     ic-ELISA     substrate     chromatography    

Nodal, zonal, or uniform electricity pricing: how to deal with network congestion

Martin WEIBELZAHL

《能源前沿(英文)》 2017年 第11卷 第2期   页码 210-232 doi: 10.1007/s11708-017-0460-z

摘要: In this paper, the main contributions to congestion management and electricity pricing, i.e., nodal, zonal, and uniform electricity pricing, are surveyed. The key electricity market concepts are structured and a formal model framework is proposed for electricity transportation, production, and consumption in the context of limited transmission networks and competitive, welfare maximizing electricity markets. In addition, the main results of existing short-run and long-run congestion management studies are explicitly summarized. In particular, the important interconnection between short-run network management approaches and optimal long-run investments in both generation facilities and network lines are highlighted.

关键词: nodal pricing     zonal pricing     uniform pricing     competitive electricity markets     welfare maximization     redispatch     optimization models    

Contributions of adsorption, bioreduction and desorption to uranium immobilization by extracellular polymeric

《环境科学与工程前沿(英文)》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1707-z

摘要:

● EPS immobilizes U(VI) via adsorption, bioreduction and desorption.

关键词: Adsorption     Bioreduction     Desorption     Kinetics     Isotherm     Uranium    

运用自组织竞争网络进行气体定性分析的研究

太惠玲,谢光忠,蒋亚东

《中国工程科学》 2006年 第8卷 第1期   页码 81-84

摘要:

优选了分析H2,CO气体的半导体气体传感器组成阵列,建立了实时数据采集系统,并与自组织竞争网络模式识别技术相结合,以进行气体定性分析的研究;同时为了消除气体浓度变化对传感器阵列输出的影响,提高自组织网络的识别效果,运用三种不同的数据归一化算法对传感器阵列的输出响应进行了预处理,并对各自对应的网络识别结果进行了分析与讨论。实验结果表明,采用相对算法可实现H2,CO气体的准确识别。

关键词: 气体传感器阵列     自组织竞争网络     定性分析    

Polypropylene microplastics alter the cadmium adsorption capacity on different soil solid fractions

《环境科学与工程前沿(英文)》 2022年 第16卷 第1期   页码 3-3 doi: 10.1007/s11783-021-1437-z

摘要:

Microplastics (MPs) are widely present in a variety of environmental media and have attracted more and more attention worldwide. However, the effect of MPs on the interaction between heavy metals and soil, especially in soil solid fraction level, is not well understood. In this study, batch experiments were performed to investigate the adsorption characteristics of Cd in bulk soil and three soil solid fractions (i.e. particulate organo matter (POM), organic-mineral compounds (OMC), and mineral) with or without polypropylene (PP) MPs.

关键词: Polypropylene microplastics     Cadmium     Adsorption     POM     OMC     Mineral    

Cesium removal from radioactive wastewater by adsorption and membrane technology

《环境科学与工程前沿(英文)》 2023年 第18卷 第3期 doi: 10.1007/s11783-024-1798-1

摘要:

● Removal of cesium from radioactive wastewater is still a challenging.

关键词: Cesium     Adsorption     Membrane separation     Advanced liquid processing system     Fukushima nuclear accident    

Dual-functional sites for synergistic adsorption of Cr(VI) and Sb(V) by polyaniline-TiO hydrate: Adsorption

《环境科学与工程前沿(英文)》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1526-7

摘要:

• PANI/Ti(OH)n(4n)+ exhibited excellent adsorption capacity and reusability.

关键词: Polyaniline/TiO2     Chromium     Antimony     Adsorption     Desorption     Mechanism    

标题 作者 时间 类型 操作

Competitive adsorption and desorption of copper and lead in some soil of North China

Fengjie ZHANG, Xiaoxia OU, Shuo CHEN, Chunqiu RAN, Xie QUAN

期刊论文

Immobilized

Pei MA, Dan ZHANG

期刊论文

Adsorption of sulfonamides on lake sediments

Zhenxing ZHONG, Jian XU, Yuan ZHANG, Lei LI, Changsheng GUO, Yan HE, Wenhong FAN, Beiping ZHANG

期刊论文

Effect of co-existing organic compounds on adsorption of perfluorinated compounds onto carbon nanotubes

Shubo DENG,Yue BEI,Xinyu LU,Ziwen DU,Bin WANG,Yujue WANG,Jun HUANG,Gang YU

期刊论文

CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

期刊论文

Knowledge-based competitive strategy using direct customer experience for automobile product development

Peter HODGES, Shuh Yuan LIOU,

期刊论文

基于产业价值链的我国制造业竞争战略研究

赵文成,赵红

期刊论文

Optimal production strategy for auto manufacturers with government subsidies in competitive environments

期刊论文

Microcystin-LR detection based on indirect competitive enzyme-linked immunosorbent assay

SHENG Jianwu, HE Miao, YU Shaoqing, SHI Hanchang, QIAN Yi

期刊论文

Nodal, zonal, or uniform electricity pricing: how to deal with network congestion

Martin WEIBELZAHL

期刊论文

Contributions of adsorption, bioreduction and desorption to uranium immobilization by extracellular polymeric

期刊论文

运用自组织竞争网络进行气体定性分析的研究

太惠玲,谢光忠,蒋亚东

期刊论文

Polypropylene microplastics alter the cadmium adsorption capacity on different soil solid fractions

期刊论文

Cesium removal from radioactive wastewater by adsorption and membrane technology

期刊论文

Dual-functional sites for synergistic adsorption of Cr(VI) and Sb(V) by polyaniline-TiO hydrate: Adsorption

期刊论文